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For the TV screen size, were you able to find the scaling or overscan settings in your video card's control panel applet? If not, one other thing you can try is setting your TV's aspect ratio to "Just Scan" instead of "16:9." Not all TVs have that option though.
If Windows is moving your applications to the TV when switching profiles, the best thing to do is use the DisplayFusion Save and Restore Window Positions functions. On the Settings > Functions tab, assign key combos to those, then save the positions before switching, and restore them after the profile has been loaded. If this works for you, it can be scripted into a single DisplayFusion function as well. Just let me know