Is it possible to set a compatibility option for a specific application so that the application is excluded from having child windows moved?

I like having the "Center child windows over the parent window" option enabled, but I have one application that I would like to exclude from this behavior. On the Compatibility tab, I could not locate an option to disable that specific feature.

Is there some sort of work-around? If not, is it possible to add this feature to the list of options on the Compatibility tab?

Thanks for the feedback!
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Jeremy