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You can do this by right clicking on a screen and then on screen settings (I think its called that) then Your main screen should be No1, drag the other screens around so they are numbered the way you want the windows to snap/move.
For example my 3 screen setup is No3 - No1 - No2 and if I use the Winkey + arrows then it will scroll through the screens in that order (to the right).
An example of yours assuming you want the main screen on the bottom row and in the middle would be
No4 - No5 - No6
No3 - No1 - No2
It should now move through the screens to the right then up to the second or upper row but you can drag them around to suit your needs in any order and the scroll momentum will always be (or should always be) 1 to 6